Chemical Engineering @ChemengFiles.Com

This program was developed by two professors at the University of Texas Tech, Dr. Theodore Wiesner of the department of chemical engineering and Dr. William Lan from the department of educational psychology. This virtual laboratory consists of three teams: a cooling tower, a heat exchanger and a packed column for absorption of ammonia. LabVIEW was used as an interface.

In this work the synthesis, characterization, and gas transport properties of hydrogen selective silica membranes were studied along with the catalytic reforming of CH4 with CO2 (CH4 + CO z 2 CO + 2 H2) in a hydrogen separation membrane reactor. The silica membranes were prepared by chemical vapor deposition (CVD) of a thin SiO2 layer on porous supports (Vycor glass and alumina) using thermal decomposition of tetraethylorthosilicate (TEOS) in an inert atmosphere. These membranes displayed high hydrogen permeances (10-8 � 10-7 mol m-2 s-1 Pa-1) and excellent H2 selectivities (above 99.9 %) over other gases (CH4, CO, and CO2). The membranes were characterized using Scanning Electron Microscopy and Atomic Force Microscopy, and the mechanism of gas transport was studied applying existing theories with a newly developed treatment.

The catalytic reforming of CH4 with CO2 was carried out in a membrane reactor installed with a hydrogen separation ceramic membrane. The reaction was conducted at various pressures (1 � 20 atm) and temperatures (873 K and 923 K) at non-equilibrium conditions, and the results were compared with those obtained in a packed bed reactor in order to evaluate performance of the membrane reactor for the reaction. It was found that concurrent and selective removal of hydrogen from the reaction in the membrane reactor resulted in considerable enhancements in the yields of the reaction products, H2 and CO. The enhancements in the product yields in the membrane reactor increased with pressure showing a maximum at 5 atm, and then decreased at higher pressures. This was due to a trade-off between a thermodynamic quantity (hydrogen production by the reaction) and transport property (hydrogen separation through the membrane). It was also found that the reverse water-gas shift (RWGS) reaction occurred simultaneously with the reforming reaction giving the detrimental effect on the reaction system by reducing the amount of hydrogen production in favor of water. This was particularly significant at high pressures.

Over 40 percent of cases of colon cancer and breast cancer in some countries are preventable through healthy eating patterns, physical activity and weight maintenance, according to estimates from a report that has established recommendations for policy and measures to prevent cancer.

The report, Policy and Action for Cancer Prevention, published by the World Cancer Research Fund (WCRF) and American Institute for Cancer Research (AICR), has estimated that about 43 percent of colon cancer cases and 42 percent of cases of breast cancer in the UK could be prevented in this way.